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Aldrich
(S)-(−)-2-[(1-Hydroxy-3,3-dimethylbutan-2-ylimino)methyl]-4,6-diiodophenol
677558 -
97%
DOWNLOAD MSDS (PDF)Synonym: 2-[[[(1S)
CAS Number: 477339-39-2
Empirical Formula (Hill Notation): C13H17I2NO2
Molecular Weight: 473.09
MDL number: MFCD09038443
PubChem Substance ID: 24885382
![(S)-(−)-2-[(1-Hydroxy-3,3-dimethylbutan-2-ylimino)methyl]-4,6-diiodophenol 97%](/medium/structureimages/43/mfcd09038443.png)
Properties
| Related Categories | Asymmetric Synthesis, Chiral Catalysts, Ligands, and Reagents, Oxidation |
| assay | 97% |
| optical activity | [α]20/D -19°, c = 3% in acetone |
| mp | 164-168 °C |
Description
Application
Useful in catalytic asymmetric sulfoxidation of alkyl aryl sulfides1 and in the kinetic resolution of alkyl aryl sulfoxides.2
Packaging
100, 500 mg in glass btl
Price and Availability
Safety Information
| Symbol |  GHS06 |
| Signal word | Danger |
| Hazard statements | H301-H315-H319-H335 |
| Precautionary statements | P261-P301 + P310-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US), Eyeshields, Faceshields, Gloves |
| Hazard Codes | Xn |
| Risk Statements | 22-36/37/38 |
| Safety Statements | 26 |
| WGK Germany | 3 |
Technical information & documentation associated with this product is available in the Safety & Documentation tab.
Articles
Asymmetric 1,3-dipolar Cycloaddition Using Fesulphos
The asymmetric 1,3-dipolar cycloaddition reaction is of the utmost importance for the enantioselective synthesis of five-membered heterocycles. Cabrera et al. introduced a new family of ligands consi...
William Sommer
Aldrich ChemFiles 2008, 8.6, 14.
Keywords: 1,3-Dipolar cycloaddition, Asymmetric synthesis, Catalysis, Cycloadditions, Ligands
Asymmetric Oxidation of Di-tert-butyl Disulfide
The seminal work of Ellman and coworkers provided the first example of the catalytic asymmetric oxidation of tert-butyl disulfide. The desymmetrization involves reaction of tert-butyl disulfide with ...
William Sommer
Aldrich ChemFiles 2008, 8.6, 14.
Keywords: Asymmetric synthesis, Catalysis, Desymmetrizations, Ligands, Oxidations, Solvents
Gleason Chiral Auxiliary
The stereocontrolled synthesis of all-carbon quaternary centers is a formidable challenge in asymmetric synthesis. Alkylation of an enolate is a fundamental reaction that may be used towards this tas...
Aldrich ChemFiles 2006, 6.10, 10.
Keywords: Alkylations, Arylations, Asymmetric synthesis, Catalysis, Chiral auxiliaries
References
1. Pelotier, B. et al. Synlett, 1055, (2002)
2. Drago, C. et al. Angew. Chem. Int. Ed. Engl. 44, 7221, (2005) Abstract
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